{"text_format":"1","workbook":"xlsx","n_sheets":2,"sheets":["Calculator","Gibbs Free Energy Data"],"not_rendered":{"charts":0,"images":0,"macros":1,"external_links":0,"defined_names":11,"comments":0,"pivot_tables":0},"unopened":[],"bounds":{"document_bytes":16777216,"sheet_cells":100000,"rows_first":2000,"rows_last":500,"rows_between":2000,"halvings":0,"cell_chars":16384,"cell_head_chars":4096},"cells_cut":0,"cells_raw":0,"read":"whole","date_system":"1900"}

{"sheet":"Calculator","index":0,"n_rows":31,"n_cols":10,"rows_kept":31,"cut":false,"hidden":false,"merged":[[16,6,19,10],[22,0,22,10],[27,0,28,10],[30,0,31,10],[21,0,21,10],[25,0,25,10],[11,2,11,3],[1,0,1,5],[1,7,1,9],[4,7,4,9],[7,6,7,10],[10,6,13,10]]}
[]
["Gibbs' Free Energy of Reaction",null,null,null,null,null,null,"Number of Electrons Exchanged (n)"]
[null,null,null,null,null,null,null,null,1]
[null,"Reactant","LiCl"]
[null,"Stoichometry",1,0,null,null,null,"Faraday's Constant (F)"]
[null,"ΔG (kJ mol-1)",-344.90217000000001,0,null,null,null,null,96485,"C/mol e-"]
[null,0,0]
[null,"Product","Li(l)","Cl2(g)",null,null,"E0 vs. Anodic Half-Cell Rxn (e.g., Cl2 +2e- = 2Cl-)"]
[null,"Stoichiometry",1,0.5,1,null,null,null,{"$f":"D14*1000/-n/F","v":-3.5746713996994348},"V"]
[null,"Stoichometry",0,0,0]
[null,null,null,null,null,null,"Note: This assumes a pure reference state (i.e., mole fraction of 1). If the species is dilute, the equilibrium potential may vary significantly from E0"]
[null,null,"Temperature (K) ",null,773]
[]
[null,null,"ΔG(rxn)",{"$f":"C9*C10+D9*D10+E10*E9-C6*C5-D6*D5-E6*E5","v":344.90217000000001},"kJ mol-1"]
[]
[null,null,null,null,null,null,"This calculator is based on the method presented in this article:"]
[null,null,null,null,null,null,"Zhang, W., Pulham, C. R., Mount, A. R., Brockie, N., & Lewin, R. (2008). Thermodynamic calculation and reference electrode calibration for high temperature molten salts. Energy Materials, 3(2), 132–136. https://doi.org/10.1179/174892408X394254 "]
[]
[]
[]
[]
["Gibbs Free Energy and Standard Potential Estimator by Devin Rappleye"]
["Download the original source file from https://pyro.byu.edu/electrochemistry-tools"]
[]
["Notes:"]
["Pre-Loaded Gibbs Free Enegy Data is from: Barin, I. (1995). Thermochemical Data of Pure Substances (3rd ed.). VCH Verlagsgesellschaft mbH."]
[]
["Users may add data on the Gibbs Free Energy Tab. The existing pattern must be followed exactly for the macro to continue to work. This includes indication liquid with (l) and gas with (g)."]
[]
[]
["This is a simple estimation tool and doesn't calculate the hypothetical supercooled liquid reference state when estimating standard potentials. This may introduces some error on the order of 10-100 mV."]

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