Chapter 2 of my dissertation - This chapter discusses and derives some fundamental electrochemical relations from principles and relations commonly taught to undergraduate chemical engineers.
A couple of important concepts to try and keep straight in electrochemistry:
Chemical reversibility and electrochemical reversibility (A good explanation can be found here)
Soluble-soluble: The reactant and the product of an electrochemical reaction is soluble in the solution (e.g., Cr3+ + 1e- = Cr2+)
Soluble-insoluble: The reactant of an electrochemical reaction is soluble in solution, but the product is not soluble in the solution (e.g., La3+ + 3e- = La, where La is not soluble in the solution being used)
Cyclic Voltammetry (soluble-soluble)
Online Tutorial and Simulation - This tool provides a web interface for simulating soluble-soluble cyclic voltammograms. It also provide breif explanation of the electrochemical relations and equations involved in the simulation. Just keep in mind, that this is specific to soluble-soluble reactions