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Department of Chemical Engineering
PyRO Lab and Research Group

Publications

Journal Articles
Conferences
Patent Applications
Theses/Dissertations

Peer-Reviewed Journal Articles

  1. Schvaneveldt, M., Fuller, R., & Rappleye, D. (2022). Electroanalytical measurements of lanthanum (III) chloride in molten calcium chloride and molten calcium chloride and lithium chloride. Journal of Electroanalytical Chemistry, 918, 116442. https://doi.org/10.1016/j.jelechem.2022.116442 | Pre-Print
  2. Fuller, R., Williams, T., Schvaneveldt, M., & Rappleye, D. (2022). A comparison of square-wave voltammetry models to determine the number of electrons exchanged in metal deposition. Electrochimica Acta, 414, 140220. https://doi.org/10.1016/j.electacta.2022.140220 | Pre-print
  3. Williams, T., Shum, R., & Rappleye, D. (2021). Concentration Measurements In Molten Chloride Salts Using Electrochemical Methods. Journal of The Electrochemical Society, 168(12), 123510. https://doi.org/10.1149/1945-7111/ac436a | Open Access
  4. Zhang, C., Rappleye, D., Nelson, A., Simpson, S., & Simpson, M. (2021). Electroanalytical Measurements of Oxide Ions in Molten CaCl2 on W electrode. Journal of The Electrochemical Society, 168(9), 097502. https://doi.org/10.1149/1945-7111/ac208e | Pre-Print
  5. Rappleye, D., & Haun, R. (2021). Production of Pure Vanadium: Industry Review and Feasibility Study of Electron Beam Melt Refining of V–Al Alloys. Journal of Sustainable Metallurgy, 7(3), 755–766. https://doi.org/10.1007/s40831-021-00407-6 | Pre-Print
  6. Rappleye, D., McNeese, J., Torres, R., Holliday, K., & Jeffries, J. R. (2021). Development of small-scale plutonium electrorefining in molten CaCl2. Journal of Nuclear Materials, 552, 152968. https://doi.org/10.1016/j.jnucmat.2021.152968 | Pre-Print
  7. Okabe, P., Rappleye, D., Newton, M., & Simpson, M. F. (2021). Development of metallic nuclear material purification process via simultaneous chlorination and volatilization. Journal of Nuclear Materials, 543, 152626. https://doi.org/10.1016/j.jnucmat.2020.152626 | Pre-Print
  8. Okabe, P., Newton, M., Rappleye, D., & Simpson, M. F. (2020). Gas-solid reaction pathway for chlorination of rare earth and actinide metals using hydrogen and chlorine gas. Journal of Nuclear Materials, 534, 152156. https://doi.org/10.1016/j.jnucmat.2020.152156 | Pre-Print
  9. Horvath, D., Rappleye, D., Bagri, P., & Simpson, M. F. (2017). Electrochemical measurements of diffusion coefficients and activity coefficients for MnCl2 in molten eutectic LiCl-KCl. Journal of Nuclear Materials, 493, 189–199. https://doi.org/10.1016/j.jnucmat.2017.06.015
  10. Zhang, C., Rappleye, D., & Simpson, M. (2017). Preliminary Study of Optimization of Normal Pulse Voltammetry for Actinide Measurement in Molten Salt Electrorefiners Using LiCl-KCl-UCl3-MgCl2 as a Surrogate Salt. Journal of The Electrochemical Society, 164(8), H5218–H5223. https://doi.org/10.1149/2.0321708jes | Open Access
  11. Rappleye, D., & Simpson, M. F. (2017). Application of the rotating cylinder electrode in molten LiCl-KCl eutectic containing uranium(III)- and magnesium(II)-chloride. Journal of Nuclear Materials, 487, 362–372. https://doi.org/10.1016/j.jnucmat.2017.02.037 | Pre-Print
  12. Rappleye, D., Newton, M. L., Zhang, C., & Simpson, M. F. (2017). Electroanalytical measurements of binary-analyte mixtures in molten LiCl-KCl eutectic: Uranium(III)- and Magnesium(II)-Chloride. Journal of Nuclear Materials, 486, 369–380. https://doi.org/10.1016/j.jnucmat.2017.01.047 | Pre-Print
  13. Rappleye, D., Teaford, K., & Simpson, M. F. (2016). Investigation of the effects of uranium(III)-chloride concentration on voltammetry in molten LiCl-KCl eutectic with a glass sealed tungsten electrode. Electrochimica Acta, 219, 721–733. https://doi.org/10.1016/j.electacta.2016.10.075 | Pre-Print
  14. Wang, Z., Rappleye, D., Yang, C. S., & Simpson, M. F. (2016). Application of Voltammetry for Electroanalytical Measurement of Concentrations in LaCl3-MgCl2 Mixtures in Eutectic LiCl-KCl. Journal of The Electrochemical Society, 163(10), H921. https://doi.org/10.1149/2.0351610jes
  15. Rappleye, D., Jeong, S.-M., & Simpson, M. (2016). Electroanalytical Measurements of Binary-Analyte Mixtures in Molten LiCl-KCl Eutectic: Gadolinium(III)- and Lanthanum(III)-Chloride. Journal of The Electrochemical Society, 163(9), B507. https://doi.org/10.1149/2.1011609jes
  16. Stika, M., Rappleye, D., Simpson, M. F., & Jeong, S. M. (2016). Development of on-line pyroprocessing for liquid thorium fueled reactors. AIChE Journal, 62(4), 1236–1243. https://doi.org/10.1002/aic.15177
  17. Wang, Z., Rappleye, D., & Simpson, M. F. (2016). Voltammetric Analysis of Mixtures of Molten Eutectic LiCl-KCl Containing LaCl3 and ThCl4 for Concentration and Diffusion Coefficient Measurement. Electrochimica Acta, 191, 29–43. https://doi.org/10.1016/j.electacta.2016.01.021
  18. Bateman, K. J., Morrisona, M. C., Rappleye, D. S., Simpson, Michael. F., & Frank, S. M. (2015). Scale Up of Ceramic Waste Forms for Electrorefiner Salts Produced during Spent Fuel Treatment. Journal of Nuclear Fuel Cycle and Waste Technology, 13(Special), 55–75. https://doi.org/10.7733/jnfcwt.2015.13.S.55
  19. Rappleye, D., Jeong, S.-M., Gonzalez, M., Hansen, L. C., & Simpson, M. F. (2015). Application of Voltammetry to Measurement of Concentrations of Multiple Lanthanide Ions in Molten LiCl-KCl. Journal of Nuclear Fuel Cycle and Waste Technology, 13(Special), 29–38. https://doi.org/10.7733/jnfcwt.2015.13.S.29
  20. Gonzalez, M., Hansen, L., Rappleye, D., Cumberland, R., & Simpson, M. F. (2015). Application of a One-Dimensional Transient Electrorefiner Model to Predict Partitioning of Plutonium from Curium in a Pyrochemical Spent Fuel Treatment Process. Nuclear Technology, 192(2), 165–171. https://doi.org/10.13182/NT15-28
  21. Rappleye, D., Jeong, S.-M., & Simpson, M. (2015). Application of multivariate analysis techniques to safeguards of the electrochemical treatment of used nuclear fuel. Annals of Nuclear Energy, 77, 265–272. https://doi.org/10.1016/j.anucene.2014.11.023
  22. Lafreniere, P. L., Rappleye, D. S., Hoover, R. O., Simpson, M. F., & Blandford, E. D. (2015). Demonstration of Signature-Based Safeguards for Pyroprocessing as Applied to Electrorefining and the Ingot Casting Process. Nuclear Technology, 189(2), 173–185. https://doi.org/10.13182/NT14-35
  23. Rappleye, D., Stika, M., & Simpson, M. F. (2014). Simulated Response of Electrochemical Sensors for Monitoring Molten-Salt Fueled Reactors. Journal of the Institute of Nuclear Materials Management, 43(1), 50–56. | Open Access (p. 50) | Pre-Print
  24. Rappleye, D., Simpson, M., Cumberland, R., McNelis, D., & Yim, M.-S. (2014). Simulated Real-Time Process Monitoring of a Molten Salt Electrorefiner. Nuclear Engineering and Design, 273, 75–84. https://doi.org/10.1016/j.nucengdes.2014.02.024
  25. Lignell, D. O., & Rappleye, D. S. (2012). One-dimensional-turbulence simulation of flame extinction and reignition in planar ethylene jet flames. Combustion and Flame, 159(9), 2930-2943. https://doi.org/10.1016/j.combustflame.2012.03.018
  26. Ai, W., Laycock, R. G., Rappleye, D. S., Fletcher, T. H., & Bons, J. P. (2011). Effect of particle size and trench configuration on deposition from fine coal flyash near film cooling holes. Energy & Fuels, 25(3), 1066-1076. https://doi.org/10.1021/ef101375g

Conference Presentations/Proceedings (Presenter in Bold)

  1. Williams, T., Chipman, G., Fuller, R., Schvaneveldt, M., Torrie, J., & Rappleye, D. S. (2023, March). Blind Identification and Quantification of Analytes in Molten LiCl-KCl Eutectic. 152nd TMS Annual Meeting, San Diego, CA. | Abstract |
  2. Chipman, G., Johnson, B., & Rappleye, D. S. (2023, March). Electrochemical Behavior of Bismuth in molten LiCl-KCl-CaCl2. 152nd TMS Annual Meeting, San Diego, CA. | Abstract |
  3. (Invited) Fuller, M., Shum, R., & Rappleye, D. S. (2023, March). The Impact of Moisture on the Electrochemical Behavior of Molten Calcium Chloride. 152nd TMS Annual Meeting, San Diego, CA. | Abstract |
  4. Vann, C., Williams, T., & Rappleye, D. S. (2023, March). The Demonstration and Optimization of Thin-cell Electrochemical Measurements in Molten LiCl-KCl Eutectic. 152nd TMS Annual Meeting, San Diego, CA. | Abstract |
  5. (Invited) Rappleye, D., Torrie, J., Williams, T., & Fuller, R. G. (2022). Towards Electroanalytical Measurements in the Elemental Soup of Molten Salts Bearing Nuclear Fuel. ECS Meeting Abstracts, MA2022-02(58), 2193. https://doi.org/10.1149/MA2022-02582193mtgabs
  6. Fuller, R. G., Shum, R., Calabuig, S., & Rappleye, D. (2022). The Construction and Validation of Rotating Electrodes in Molten Salts for the Measurement of Hydrodynamic Properties and Corrosion. ECS Meeting Abstracts, MA2022-02, 2059. https://doi.org/10.1149/MA2022-02552059mtgabs
  7. Chipman, G. D., Johnson, B., Zhang, C., Choi, S., Simpson, M., & Rappleye, D. S. (2022, May). Determining a Suitable Surrogate for Actinide Electrorefining, Actinide Separations Conference, Los Alamos, NM
  8. Rappleye, D., Willliams, T., Fuller, R., & Schvaneveldt M. (2022, May). The Role of Electroanalytical Techniques in Studying and Monitoring Actinides in Molten Salt Based Operations, Actinide Separations Conference, Los Alamos, NM
  9. Schvaneveldt, M., Monson, J., Fuller, R., & Rappleye, D. (2022, May). In-Situ Chlorine Oxidation for Chlorination and Purification of Rare Earth Metals, Actinide Separations Conference, Los Alamos, NM
  10. Fuller, R. G., Williams, T., Schvaneveldt, M., & Rappleye, D. (2022). Analysis of Techniques for Determining the Number of Electrons Exchanged in Square-Wave Voltammetry. ECS Meeting Abstracts, MA2022-01(45), 1907. https://doi.org/10.1149/MA2022-01451907mtgabs | Slides
  11. Fuller, R. G., Rappleye, D., Williams, T., & Schvaneveldt, M. (2021, October). Analysis on Methods for Determining the Number of Electrons Exchanged in a Metal Deposition Reaction through Square-Wave Voltammetry. In ECS Meeting Abstracts (No. 54, p. 1921). IOP Publishing.
  12. Schvaneveldt, M., Rappleye, D., & Fuller, R. G. (2021, October). Electroanalytical Measurements of Lanthanum (III) Chloride in Molten Calcium Chloride and Molten Eutectic Calcium Chloride and Lithium Chloride. In ECS Meeting Abstracts (No. 21, p. 1909). IOP Publishing.
  13. Zhang, C., Rappleye, D. S., Wallace, J., & Simpson, M. (2018, October). Electrochemical Analysis of Bi-Analyte Electrorefiner Salt with High Concentration of UCl3. 2018 AIChE Annual Meeting, Pittsburg, PA. | Abstract
  14. Oakbe, P., Rappleye, D., & Simpson, M. (2018, June). Effects of Changing Parameters on Chlorination Process of Rare Earth Metals and Actinides Mixture. Transactions of the American Nuclear Society. 2018 ANS Annual Meeting, Philadelphia, PA. | Link to Conference Paper
  15. Rappleye, D., Horvath, D., Wang, Z., Zhang, C., & Simpson, M. F. (2016). Methods for determining the working electrode interfacial area for electroanalytical measurements of metal ions in molten LiCl-KCl. ECS Transactions, 75(15), 79. | Link to Conference Paper
  16. Zhang, C., Rappleye, D., & Simpson, M. F. (2016). Development and Optimization of Voltammetry for Real Time Analysis of Multi-Component Electrorefiner Salt. ECS Transactions, 75(15), 95.
  17. Rappleye, D., & Simpson, M. F. (2015, July). Electrochemical Signal Measurement and Analysis for Metal Deposition in Molten LiCl-KCl Eutectic. In INMM 56th Annual Meeting, Palm Springs, CA.

Patent Applications

  1. Rappleye, Devin, and Chao Zhang. "Production of carbon products in molten salt media." U.S. Patent Application 16/745,181, filed July 23, 2020.

  2. Simpson, Michael, Devin Rappleye, and Kevin Teaford. "Fixed area electrode for electrochemical analysis of high temperature fluids." U.S. Patent Application 15/711,894, filed March 22, 2018.

Theses/Dissertations

  1. Schvaneveldt, M. (2022). In-Situ Chlorine Gas Generation for Chlorination and Purification of Rare Earth and Actinide Metals (Master's Thesis, Brigham Young University). Link
  2. Rappleye, D. S. (2016). Electrochemical concentration measurements for multianalyte mixtures in simulated electrorefiner salt (Doctoral dissertation, The University of Utah). Link
  3. Rappleye, D. (2012). Developing safeguards for pyroprocessing: detection of a plutonium Co-deposition on solid cathode in an electrorefiner by applying the signature-based safeguards approach (Master's Thesis, North Carolina State University). Link